The caliber is a unit of length based on the inch (imperial units) and uses the symbol cl.
It represents the internal diameter of a gun barrel and therefore more often than not, the size of the ammunition or round that gun requires to fire.
It is not always represented or converted exactly in inches so a table or "well-known" conversions are often used to depict measurements / ammo types instead.
The parsec is a unit of length and is used in the Astronomical system of units. It is denoted by the symbol pc.
It is equal to 3.26156 ly (light years) which is approximately 31 trillion kilometres (19 trillion miles). It's used to measure huge distances to objects and planets outside of our Solar System.
It was first brought into use by Herbert Hall Turner (a British Astronomer) in 1913 and was invented to use in calculations of astronomical distances to make it easier in calculations using raw data.