The angstrom (or ångström) is a unit of length and is a non-SI but metric accepted unit with the symbol Å.
It is equal in length to one ten-billionth of a metre or 0.1 nanometres (0.1nm).
It is approximately the size of an atom and is mostly used to measure very small distances for example wavelengths of light.
The caliber is a unit of length based on the inch (imperial units) and uses the symbol cl.
It represents the internal diameter of a gun barrel and therefore more often than not, the size of the ammunition or round that gun requires to fire.
It is not always represented or converted exactly in inches so a table or "well-known" conversions are often used to depict measurements / ammo types instead.