The light year is a unit of length in the Astronomical system of units. It uses the symbol ly.
Often confused with a unit of time as it contains the word "year", it is actually defined by the International Astronomical Union (IAU) as the amount of distance that light travels in a vacuum in one Julian year (365.25 days).
Using the speed of light (299,792,458 m/s or 'c') and the Julian year (as apposed to the Gregorian year which is 365.2425 days), we can equivalate 1 light year as 9,460,730,472,580,800 metres or ≈ 9.46 trillion kilometres.
The em is a unit of length in the field of typography and uses the symbol em.
It is a "relative" unit and equals the currently specified point size. For example, 1 em in a 24-point typeface is equal to 24 points. This allows a typographer to specify text size relative to a base figure.
In metal type, the em was equal to the line height of the metal body. This meant the physical size of the letter could not exceed the em. In digital type, the em is a grid of arbitrary resolution so can be scaled to any point size for screen or print.