The caliber is a unit of length based on the inch (imperial units) and uses the symbol cl.
It represents the internal diameter of a gun barrel and therefore more often than not, the size of the ammunition or round that gun requires to fire.
It is not always represented or converted exactly in inches so a table or "well-known" conversions are often used to depict measurements / ammo types instead.
The nanometre is a unit of length and is a multiple of the SI unit metre. It uses the symbol nm.
1 nm is equal to one one-billionth of a metre. (Nano is the prefix for one billionth). It is used to express dimensions on an atomic scale for example a helium atom has a radius of approximately 0.03nm.
The nanometre was previously known as the millimicrometre (or the millimicron).