The parsec is a unit of length and is used in the Astronomical system of units. It is denoted by the symbol pc.
It is equal to 3.26156 ly (light years) which is approximately 31 trillion kilometres (19 trillion miles). It's used to measure huge distances to objects and planets outside of our Solar System.
It was first brought into use by Herbert Hall Turner (a British Astronomer) in 1913 and was invented to use in calculations of astronomical distances to make it easier in calculations using raw data.
The em is a unit of length in the field of typography and uses the symbol em.
It is a "relative" unit and equals the currently specified point size. For example, 1 em in a 24-point typeface is equal to 24 points. This allows a typographer to specify text size relative to a base figure.
In metal type, the em was equal to the line height of the metal body. This meant the physical size of the letter could not exceed the em. In digital type, the em is a grid of arbitrary resolution so can be scaled to any point size for screen or print.