The league is a ancient unit of length that doesn't below to a unit system. Its symbol is simply - league.
It was originally an ancient Celtic unit as well as being common in Latin America and meant the distance "a person could walk in an hour". It is no longer a recognised unit in any nation.
Once it started to be quantified, in Argentina (legua) it represented 5.572 km, in England it was quantified as 3 miles and at sea a league is 3 nautical miles (3.452 miles).
The em is a unit of length in the field of typography and uses the symbol em.
It is a "relative" unit and equals the currently specified point size. For example, 1 em in a 24-point typeface is equal to 24 points. This allows a typographer to specify text size relative to a base figure.
In metal type, the em was equal to the line height of the metal body. This meant the physical size of the letter could not exceed the em. In digital type, the em is a grid of arbitrary resolution so can be scaled to any point size for screen or print.